Mechanochemical synthesis of crystalline and amorphous digold(I) helicates exhibiting anion- and phase-switchable luminescence properties.
نویسندگان
چکیده
For the first time, mechanochemical synthesis has been used for the preparation of crystalline and amorphous dinuclear gold(i) helicates, [Au2L2](X)2 (L = xantphos; X = CF3SO3, SCN, BF4 and PF6), that show anion- and phase-switchable luminescence properties. This solid-state approach provides strategies for developing switchable luminescent materials.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 31 شماره
صفحات -
تاریخ انتشار 2014